I like to use witchhazel to rinse my face with (and sometimes my arms after work--I just get pimples like crazy on the backs of my arms for some reasono and washing with witch hazel helps a lot).
This is a great resource. They also have an annual review of sunscreens that is invaluable.
I also like oils for cleansing and moisturizing. Plain olive oil can be used to cleanse, and coconut oil is a good moisturizer. Another good oil is jojoba. It's chemically the closest to the oil your skin naturally produces: sebum.
I like to use witchhazel to rinse my face with (and sometimes my arms after work--I just get pimples like crazy on the backs of my arms for some reasono and washing with witch hazel helps a lot).