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Anyway on topic: yeah we really don't want megadoses of vitamin antioxidants at all. It doesn't seem to matter when in the day we take them, it kills the adaptation to exercise. http://www.pnas.org/content/106/21/8665.long
Vegetables, grassfed meats, eggs, and other sources of vitamin c and e will be enough. Since vitamin e is fat-soluble a smarter strategy would be to take something like 800IU of mixed tocopherols once a week on a light or no exercise day.